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詹氏菌属对芴、二苯醚、二苯并对二恶英和咔唑的生物转化

Biotransformation of fluorene, diphenyl ether, dibenzo-p-dioxin and carbazole by Janibacter sp.

作者信息

Yamazoe Atsushi, Yagi Osami, Oyaizu Hiroshi

机构信息

Graduate School of Agricultural and Life Sciences, The University of Tokyo, Bunkyo-ku, Tokyo 113-8657, Japan.

出版信息

Biotechnol Lett. 2004 Mar;26(6):479-86. doi: 10.1023/b:bile.0000019554.49484.40.

Abstract

Fluorene, diphenyl ether, dibenzo-p-dioxin, and carbazole were used by a dibenzofuran-utilizing Janibacter sp. strain YY-1. Metabolites were identified by GC-MS. Angular dioxygenation was the major pathway for degradation of fluorene, diphenyl ether, and dibenzo-p-dioxin but not for carbazole. Lateral dioxygenation of all tested compounds was indicated by the detection of mono- or di-hydroxylated compounds. The bacterium also catalyzed the monooxygenation of fluorene at the C9 position.

摘要

利用二苯并呋喃的詹氏菌属菌株YY-1可利用芴、二苯醚、二苯并对二噁英和咔唑。代谢产物通过气相色谱-质谱联用仪进行鉴定。角向双加氧作用是芴、二苯醚和二苯并对二噁英降解的主要途径,但咔唑不是。通过检测单羟基或二羟基化合物表明了所有测试化合物的侧向双加氧作用。该细菌还催化了芴在C9位的单加氧作用。

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