胺的动力学拆分：一种具有独特溶剂诱导立体选择性反转的高对映选择性和化学选择性乙酰化试剂。 - Suppr

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超能文献

Kinetic resolution of amines: a highly enantioselective and chemoselective acetylating agent with a unique solvent-induced reversal of stereoselectivity.

作者信息

Arseniyadis Stellios, Valleix Alain, Wagner Alain, Mioskowski Charles

机构信息

Laboratoire de Synthèse Bioorganique, UMR 7514 du CNRS, Faculté de Pharmacie, 74 route du Rhin, 67400 Illkirch, France.

出版信息

Angew Chem Int Ed Engl. 2004 Jun 21;43(25):3314-7. doi: 10.1002/anie.200453956.

DOI:10.1002/anie.200453956

PMID:15213962

Abstract

摘要

相似文献

Kinetic resolution of amines: a highly enantioselective and chemoselective acetylating agent with a unique solvent-induced reversal of stereoselectivity.胺的动力学拆分：一种具有独特溶剂诱导立体选择性反转的高对映选择性和化学选择性乙酰化试剂。

Angew Chem Int Ed Engl. 2004 Jun 21;43(25):3314-7. doi: 10.1002/anie.200453956.

Unprecedented, fully recyclable, solid-supported reagent for the kinetic resolution of racemic amines through enantioselective N-acetylation.用于外消旋胺对映选择性N-乙酰化动力学拆分的前所未有的、完全可回收的、固相支持试剂。

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Chemodivergence in enantioselective desymmetrization of diazabicycles: ring-opening versus reductive arylation.二氮杂环化合物对映选择性去对称化中的化学发散：开环与还原芳基化。

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A formal [3 + 3] cycloaddition reaction. 5. An enantioselective intramolecular formal aza-[3 + 3] cycloaddition reaction promoted by chiral amine salts.一种形式上的[3 + 3]环加成反应。5. 手性胺盐促进的对映选择性分子内形式上的氮杂-[3 + 3]环加成反应。

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Study of aromatic nucleophilic substitution with amines on nitrothiophenes in room-temperature ionic liquids: are the different effects on the behavior of para-like and ortho-like isomers on going from conventional solvents to room-temperature ionic liquids related to solvation effects?室温离子液体中胺对硝基噻吩的芳香亲核取代反应研究：从传统溶剂到室温离子液体，对位异构体和邻位异构体行为的不同影响与溶剂化效应有关吗？

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Chiral recognition and kinetic resolution of aromatic amines via supramolecular chiral nanocapsules in nonpolar solvents.手性识别和动力学拆分芳胺通过超分子手性纳米胶囊在非极性溶剂中。

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Highly enantioselective michael addition of cyclic 1,3-dicarbonyl compounds to alpha,beta-unsaturated ketones.环状1,3 - 二羰基化合物对α,β - 不饱和酮的高度对映选择性迈克尔加成反应。

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Origin of enantioselectivity reversal in Lewis acid-catalysed Michael additions relying on the same chiral source.基于相同手性源的路易斯酸催化迈克尔加成反应中对映选择性反转的起源。

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Stereoelectronic basis for the kinetic resolution of N-heterocycles with chiral acylating reagents.使用手性酰化试剂对氮杂环进行动力学拆分的立体电子基础。

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Peptide-catalyzed kinetic resolution of formamides and thioformamides as an entry to nonracemic amines.肽催化的酰胺和硫代酰胺的动力学拆分作为获得非对映胺的一种方法。

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