Closson Adam, Johansson Mikael, Bäckvall Jan-E
Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, SE-106 91 Stockholm, Sweden.
Chem Commun (Camb). 2004 Jul 7(13):1494-5. doi: 10.1039/b403333g. Epub 2004 May 24.
A biomimetic catalytic system for dihydroxylation of olefins consisting of OsO4, N-methylmorpholine, and a flavin has been immobilized in an ionic liquid. This immobilized catalytic system is highly efficient for dihydroxylation with 30% aqueous H2O2 and it can be reused (at least 5 times) without loss of activity.
一种由四氧化锇、N-甲基吗啉和黄素组成的用于烯烃二羟基化的仿生催化体系已被固定在离子液体中。这种固定化催化体系对于用30%的过氧化氢水溶液进行二羟基化反应非常高效，并且可以重复使用（至少5次）而不损失活性。
