Kofoed Jacob, Machuqueiro Miguel, Reymond Jean-Louis, Darbre Tamis
Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, CH-3012, Bern, Switzerland.
Chem Commun (Camb). 2004 Jul 7(13):1540-1. doi: 10.1039/b404465g. Epub 2004 May 27.
Zn-proline catalyzes the aldolisation of unprotected glycolaldehyde in water to give tetroses and hexoses; threose (33% of the product mixture) was formed with 10% enantiomeric excess of the D-isomer.
锌-脯氨酸催化未受保护的乙醇醛在水中发生羟醛缩合反应生成丁糖和己糖；形成了赤藓糖（占产物混合物的33%），其D-异构体的对映体过量为10%。
