Poddar Roona, Jain Arti, Kidwai Mazaahir
Department of Chemistry, University of Delhi, Delhi 110007, India.
Department of Chemistry, Daulat Ram College, University of Delhi, Delhi 110007, India.
J Adv Res. 2017 May;8(3):245-270. doi: 10.1016/j.jare.2016.12.005. Epub 2017 Jan 9.
Under the green chemistry perspective, bis[(l)prolinate-N,O]Zn (also called zinc-proline or Zn[(l)-pro]) has proven its competence as a promising alternative in a plethora of applications such as catalyst or promoter. Owing to its biodegradable and non-toxic nature of bis[(l)prolinate-N,O]Zn, it is being actively investigated as a water soluble green catalyst for synthetic chemistry. Bis[(l)prolinate-N,O]Zn are readily utilized under mild conditions and have high selectivity and reactivity with broad range of substrate acceptance to make it better reaction medium for a wide variety of organic transformations. This Review summarizes the till date literature on its synthesis, characterization, and its catalytic role in various organic reactions.
从绿色化学的角度来看,双[(L)-脯氨酸根-N,O]锌(也称为脯氨酸锌或Zn[(L)-脯氨酸])已证明其在众多应用中作为有前途的替代品的能力,例如催化剂或促进剂。由于双[(L)-脯氨酸根-N,O]锌具有可生物降解和无毒的性质,它正作为合成化学中的水溶性绿色催化剂被积极研究。双[(L)-脯氨酸根-N,O]锌在温和条件下易于使用,对广泛的底物具有高选择性和反应性,使其成为各种有机转化的更好反应介质。本综述总结了迄今为止关于其合成、表征及其在各种有机反应中的催化作用的文献。