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双[(l)-脯氨酸根-N,O]锌:一种用于各种有机转化的水溶性可循环催化剂。

Bis[(l)prolinate-N,O]Zn: A water-soluble and recycle catalyst for various organic transformations.

作者信息

Poddar Roona, Jain Arti, Kidwai Mazaahir

机构信息

Department of Chemistry, University of Delhi, Delhi 110007, India.

Department of Chemistry, Daulat Ram College, University of Delhi, Delhi 110007, India.

出版信息

J Adv Res. 2017 May;8(3):245-270. doi: 10.1016/j.jare.2016.12.005. Epub 2017 Jan 9.

Abstract

Under the green chemistry perspective, bis[(l)prolinate-N,O]Zn (also called zinc-proline or Zn[(l)-pro]) has proven its competence as a promising alternative in a plethora of applications such as catalyst or promoter. Owing to its biodegradable and non-toxic nature of bis[(l)prolinate-N,O]Zn, it is being actively investigated as a water soluble green catalyst for synthetic chemistry. Bis[(l)prolinate-N,O]Zn are readily utilized under mild conditions and have high selectivity and reactivity with broad range of substrate acceptance to make it better reaction medium for a wide variety of organic transformations. This Review summarizes the till date literature on its synthesis, characterization, and its catalytic role in various organic reactions.

摘要

从绿色化学的角度来看,双[(L)-脯氨酸根-N,O]锌(也称为脯氨酸锌或Zn[(L)-脯氨酸])已证明其在众多应用中作为有前途的替代品的能力,例如催化剂或促进剂。由于双[(L)-脯氨酸根-N,O]锌具有可生物降解和无毒的性质,它正作为合成化学中的水溶性绿色催化剂被积极研究。双[(L)-脯氨酸根-N,O]锌在温和条件下易于使用,对广泛的底物具有高选择性和反应性,使其成为各种有机转化的更好反应介质。本综述总结了迄今为止关于其合成、表征及其在各种有机反应中的催化作用的文献。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/acb4/5338870/ff8f3289c877/fx2.jpg

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