双[μ-2-(苄基亚氨基甲基)-4-氯苯酚根合]双[氯化铜(II)]
Bis[μ-2-(benzyl-imino-meth-yl)-4-chloro-phenolato]bis[chloridocopper(II)].
作者信息
Pu Xiaohua, Zhang Xinli, Li Zongxiao
机构信息
Department of Chemistry, Baoji University of Arts and Science, Baoji, Shaanxi 721007, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 18;64(Pt 1):m216. doi: 10.1107/S1600536807061764.
The title complex, [Cu(2)(C(14)H(11)ClNO)(2)Cl(2)], has a centrosymmetric dinuclear structure where two symmetry-related copper(II) metal centres are bridged by the O atoms of two phen-oxy groups. Each copper(II) centre displays a distorted tetra-hedral coordination provided by one N atom and two O atoms from two Schiff base ligands and by one Cl atom. The Cu⋯Cu separation is 3.0702 (9) Å.
标题配合物[Cu₂(C₁₄H₁₁ClNO)₂Cl₂]具有中心对称的双核结构，其中两个对称相关的铜(II)金属中心由两个苯氧基的O原子桥连。每个铜(II)中心呈现出由两个席夫碱配体的一个N原子、两个O原子以及一个Cl原子提供的扭曲四面体配位。Cu⋯Cu间距为3.0702 (9) Å。
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