Hunks William J, Ozin Geoffrey A
Materials Chemistry Research Group, Department of Chemsitry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada M5S 3H6.
Chem Commun (Camb). 2004 Nov 7(21):2426-7. doi: 10.1039/b410397a. Epub 2004 Sep 23.
A new class of periodic mesoporous organosilicas (PMOs) with 4-phenyl ether and 4-phenyl sulfide bridge-bonded silsesquioxanes integrated into the pore walls to create ligand channels have been synthesized using inorganic salt-assisted self-assembly directed by a supramolecular polyoxyethylene (10) stearyl ether (Brij 76) template.
一类新型的周期性介孔有机硅（PMO）已被合成，其孔壁中集成了4-苯基醚和4-苯基硫醚桥连的倍半硅氧烷，以形成配体通道，该合成过程采用了由超分子聚氧乙烯（10）硬脂基醚（Brij 76）模板指导的无机盐辅助自组装方法。
