Department of Chemistry, Kent State University, Kent, Ohio 44242, USA.
Chem Commun (Camb). 2010 Jul 7;46(25):4568-70. doi: 10.1039/c0cc00704h. Epub 2010 May 19.
Imine-containing bridging groups were formed during self-assembly of periodic mesoporous organosilicas by in situ dynamic covalent chemistry of aldehyde and amine groups in the presence of poly(ethylene oxide)-poly(dl-lactic acid-co-glycolic acid)-poly(ethylene oxide) block copolymer in acidic aqueous solutions.
在酸性水溶液中,通过聚(乙二醇)-聚(dl-乳酸-co-乙醇酸)-聚(乙二醇)嵌段共聚物存在下醛和胺基的原位动态共价化学,周期性介孔有机硅自组装过程中形成了含亚胺的桥联基团。