• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

Unusual reactivity of a nickel N-heterocyclic carbene complex: tert-butyl group cleavage and silicone grease activation.

作者信息

Caddick Stephen, Cloke F Geoffrey N, Hitchcock Peter B, de K Lewis Alexandra K

机构信息

Christopher Ingold Laboratories, Department of Chemistry, University College London, 20 Gordon Street, London, WC1H OAJ, UK.

出版信息

Angew Chem Int Ed Engl. 2004 Nov 5;43(43):5824-7. doi: 10.1002/anie.200460955.

DOI:10.1002/anie.200460955
PMID:15523725
Abstract
摘要

相似文献

1
Unusual reactivity of a nickel N-heterocyclic carbene complex: tert-butyl group cleavage and silicone grease activation.一种镍氮杂环卡宾配合物的异常反应性：叔丁基裂解与硅脂活化
Angew Chem Int Ed Engl. 2004 Nov 5;43(43):5824-7. doi: 10.1002/anie.200460955.
2
Comparisons between yttrium and titanium N-heterocyclic carbene complexes in the search for early transition metal NHC backbonding interactions.在寻找早期过渡金属氮杂环卡宾反馈π键相互作用中钇和钛氮杂环卡宾配合物之间的比较。
Inorg Chem. 2008 Oct 6;47(19):9042-9. doi: 10.1021/ic801046u. Epub 2008 Sep 4.
3
Amine mediated proton transfer reaction and C-Cl bond activation of solvent chloroform by a trinuclear copper(II) complex of a glucopyranosylamine derived ligand.氨基介导的质子转移反应以及由吡喃葡萄糖胺衍生配体的三核铜（II）配合物对溶剂氯仿的C-Cl键活化作用。
Dalton Trans. 2006 Aug 21(31):3742-51. doi: 10.1039/b606485j. Epub 2006 Jul 10.
4
Reactivity of a N-heterocyclic carbene, 1,3-di-(1-adamantyl) imidazol-2-ylidene, with a pseudo-acid: structural characterization of Claisen condensation adduct.
Chem Commun (Camb). 2004 Dec 21(24):2890-1. doi: 10.1039/b410986d. Epub 2004 Nov 4.
5
Synthesis and small molecule reactivity of uranium(IV) alkoxide complexes with both bound and pendant N-heterocyclic carbene ligands.具有键合和侧基N-杂环卡宾配体的铀（IV）醇盐配合物的合成及小分子反应活性
Chemistry. 2005 Oct 7;11(20):6095-9. doi: 10.1002/chem.200500481.
6
Formation and crystallographic elucidation of stable [4 + 2]-coordinate nickel(II) N,S-heterocyclic carbene (NSHC) complexes.稳定的[4 + 2]配位镍（II）N，S - 杂环卡宾（NSHC）配合物的形成及晶体学解析
Dalton Trans. 2009 Mar 14(10):1853-8. doi: 10.1039/b815876b. Epub 2009 Jan 27.
7
Noninnocent behavior of ancillary ligands: apparent trans coupling of a saturated N-heterocyclic carbene unit with an ethyl ligand mediated by nickel.辅助配体的非无害行为：镍介导的饱和N-杂环卡宾单元与乙基配体的明显反式偶联。
J Am Chem Soc. 2009 Aug 5;131(30):10461-6. doi: 10.1021/ja901346g.
8
Efficient Negishi coupling reactions of aryl chlorides catalyzed by binuclear and mononuclear nickel-N-heterocyclic carbene complexes.双核和单核镍-氮杂环卡宾配合物催化芳基氯的高效根岸偶联反应。
J Org Chem. 2008 Nov 7;73(21):8497-501. doi: 10.1021/jo8018686. Epub 2008 Oct 8.
9
The intramolecular sp2 and sp3 C-H bond activation of (p-cymene)ruthenium(II) N-heterocyclic carbene complexes.（对异丙基苯）钌（II）氮杂环卡宾配合物的分子内sp2和sp3 C-H键活化
Dalton Trans. 2009 Jul 14(26):5182-9. doi: 10.1039/b818091a. Epub 2009 May 13.
10
Activation of Di-tert-butyldiphosphatetrahedrane: Access to (tBuCP) (n=2, 4) Ligand Frameworks by P-C Bond Cleavage.二叔丁基二磷酸四面体烷的活化：通过P-C键裂解获得（tBuCP）（n = 2, 4）配体框架。
Angew Chem Int Ed Engl. 2021 Mar 15;60(12):6435-6440. doi: 10.1002/anie.202015680. Epub 2021 Feb 9.

引用本文的文献

1
Catalyst Design for Rh-Catalyzed Arene and Alkane C-H Borylation: The NHC Affects the Induction Period, and Indenyl is Superior to Cp.用于铑催化的芳烃和烷烃C-H硼化反应的催化剂设计：氮杂环卡宾影响诱导期，且茚基优于环戊二烯基。
Organometallics. 2024 Mar 28;43(9):974-986. doi: 10.1021/acs.organomet.4c00025. eCollection 2024 May 13.
2
A Silylene Stabilized by a σ-Donating Nickel(0) Fragment.由一个给予σ电子的镍(0)片段稳定的硅烯。
Angew Chem Int Ed Engl. 2022 Jul 18;61(29):e202201932. doi: 10.1002/anie.202201932. Epub 2022 May 25.
3
Reversible nickel-metallacycle formation with a phosphinimine-based pincer ligand.
基于膦亚胺的钳形配体的镍金属环可逆形成。
Dalton Trans. 2020 Jun 21;49(23):7796-7806. doi: 10.1039/d0dt01118e. Epub 2020 May 27.
4
Unexpected Vulnerability of DPEphos to C-O Activation in the Presence of Nucleophilic Metal Hydrides.在亲核金属氢化物存在下，DPEphos对C-O活化的意外脆弱性。
Chemistry. 2020 Sep 1;26(49):11141-11145. doi: 10.1002/chem.202001685. Epub 2020 Jul 28.
5
Functionalised N-Heterocyclic Carbene Ligands in Bimetallic Architectures.双金属结构中的功能化N-杂环卡宾配体
Chemistry. 2020 May 12;26(27):5927-5941. doi: 10.1002/chem.201905510. Epub 2020 Mar 18.
6
Synthesis of Symmetric and Unsymmetric Secondary Amines from the Ligand-Promoted Ruthenium-Catalyzed Deaminative Coupling Reaction of Primary Amines.从配体促进的钌催化伯胺脱氨基偶联反应中合成对称和不对称仲胺。
J Org Chem. 2018 May 4;83(9):4932-4947. doi: 10.1021/acs.joc.8b00649. Epub 2018 Apr 24.
7
Bite-angle bending as a key for understanding group-10 metal reactivity of d-[M(NHC)] complexes with sterically modest NHC ligands.咬角弯曲作为理解具有空间适度NHC配体的d-[M(NHC)]配合物中第10族金属反应性的关键。
Chem Sci. 2015 Feb 1;6(2):1426-1432. doi: 10.1039/c4sc02998d. Epub 2014 Dec 3.
8
1-(3-Ammonio-methyl-2,4,6-trimethyl-benz-yl)-3-(2,4,6-trimethyl-phen-yl)imidazol-1-ium dibromide monohydrate.二溴化 1-（3-氨甲基-2,4,6-三甲基苄基）-3-（2,4,6-三甲基苯基）咪唑-1-鎓一水合物
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 10;65(Pt 5):o1023-4. doi: 10.1107/S1600536809012811.
9
Stable cyclic carbenes and related species beyond diaminocarbenes.稳定的循环卡宾及二氨基卡宾以外的相关物种。
Angew Chem Int Ed Engl. 2010 Nov 15;49(47):8810-49. doi: 10.1002/anie.201000165.
10
Stable Bis(diisopropylamino)cyclopropenylidene (BAC) as Ligand for Transition Metal Complexes.稳定的双（二异丙基氨基）环丙烯叉（BAC）作为过渡金属配合物的配体。
J Organomet Chem. 2008 Mar 1;693(5):899-904. doi: 10.1016/j.jorganchem.2007.11.056.