镧系元素手性位移试剂用于绝对构型测定的验证：格利索普瑞宁A的全合成
Validation of lanthanide chiral shift reagents for determination of absolute configuration: total synthesis of glisoprenin A.
作者信息
Adams Christopher M, Ghosh Indranath, Kishi Yoshito
机构信息
Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA.
出版信息
Org Lett. 2004 Dec 9;6(25):4723-6. doi: 10.1021/ol048059o.
PMID:15575670
Abstract
[structure: see text] The complete stereostructure of the natural product (+)-glisoprenin A had been predicted via a novel application of chiral lanthanide shift reagents. Confirmation of the predicted stereostructure of (+)-glisoprenin A and validation of the chiral lanthanide shift approach have now been achieved through total synthesis.
摘要
[结构：见正文] 通过手性镧系位移试剂的新应用预测了天然产物(+)-格列索普宁A的完整立体结构。现在已通过全合成实现了对(+)-格列索普宁A预测立体结构的确认以及手性镧系位移方法的验证。
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