Adams Christopher M, Ghosh Indranath, Kishi Yoshito
Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA.
Org Lett. 2004 Dec 9;6(25):4723-6. doi: 10.1021/ol048059o.
[structure: see text] The complete stereostructure of the natural product (+)-glisoprenin A had been predicted via a novel application of chiral lanthanide shift reagents. Confirmation of the predicted stereostructure of (+)-glisoprenin A and validation of the chiral lanthanide shift approach have now been achieved through total synthesis.
[结构：见正文] 通过手性镧系位移试剂的新应用预测了天然产物(+)-格列索普宁A的完整立体结构。现在已通过全合成实现了对(+)-格列索普宁A预测立体结构的确认以及手性镧系位移方法的验证。
