手性镧系位移试剂在醇类绝对构型确定中的应用。
Application of chiral lanthanide shift reagents for assignment of absolute configuration of alcohols.
作者信息
Ghosh Indranath, Zeng Hongbo, Kishi Yoshito
机构信息
Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA.
出版信息
Org Lett. 2004 Dec 9;6(25):4715-8. doi: 10.1021/ol048061f.
PMID:15575668
Abstract
[structure: see text] The absolute configuration of secondary and tertiary alcohols can be predicted from analysis of the chemical shift behaviors of the CX- and CY-carbons in the presence of (R)- and (S)-Pr(tfc)3 as formulated in the boxes.
摘要
[结构：见正文] 仲醇和叔醇的绝对构型可通过分析如方框中所示，在(R)-和(S)-Pr(tfc)₃存在下CX-和CY-碳的化学位移行为来预测。
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