用于芳基格氏试剂与带有β-氢的卤代烷烃交叉偶联的铁（III）萨伦型催化剂。
Iron(III) salen-type catalysts for the cross-coupling of aryl Grignards with alkyl halides bearing beta-hydrogens.
作者信息
Bedford Robin B, Bruce Duncan W, Frost Robert M, Goodby John W, Hird Michael
机构信息
Department of Chemistry, University of Exeter, Exeter, UK EX4 4QD.
出版信息
Chem Commun (Camb). 2004 Dec 21(24):2822-3. doi: 10.1039/b413790f. Epub 2004 Oct 27.
DOI:10.1039/b413790f
PMID:15599424
Abstract
Iron(III) salen and related complexes are active catalysts for the coupling, under mild and simple reaction conditions, of aryl Grignard reagents with primary and secondary alkyl halide substrates bearing beta-hydrogens.
摘要
三价铁萨伦配合物及相关配合物是活性催化剂，可在温和且简单的反应条件下，使芳基格氏试剂与带有β-氢的伯卤代烃和仲卤代烃底物发生偶联反应。
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