铁催化的格氏试剂与具有β-氢的卤代烃的交叉偶联反应。
Iron-catalyzed Grignard cross-coupling with alkyl halides possessing beta-hydrogens.
作者信息
Nagano Takashi, Hayashi Tamio
机构信息
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan.
出版信息
Org Lett. 2004 Apr 15;6(8):1297-9. doi: 10.1021/ol049779y.
PMID:15070321
Abstract
Tris(acetylacetonato)iron(III) (Fe(acac)(3)) was found to be an efficient catalyst for the cross-coupling reaction between aryl Grignard reagents and alkyl halides possessing beta-hydrogens. The reaction is applicable to secondary alkyl halides as well as primary ones. [reaction: see text]
摘要
发现三（乙酰丙酮）铁（III）（Fe(acac)₃）是芳基格氏试剂与具有β-氢的卤代烷之间交叉偶联反应的有效催化剂。该反应适用于仲卤代烷以及伯卤代烷。[反应：见正文]
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