Bonnet Sylvestre, Collin Jean-Paul
Laboratoire de Chimie Organo-Minérale, LC 3, UMR 7177 du CNRS, Université Louis Pasteur, Faculté de Chimie, 4 rue Blaise Pascal, 67070 Strasbourg Cedex, France.
Chem Soc Rev. 2008 Jun;37(6):1207-17. doi: 10.1039/b713678c. Epub 2008 Apr 15.
In the past years, many dynamic systems often referred to as "molecular machines" have been elaborated. They are generally set in motion by external stimuli like chemical, electrochemical, or photochemical reactions. Light irradiation seems particularly promising since the input signal can be switched on and off fast and readily on a very small place. In this tutorial review, we will highlight recent advances in the design and synthesis of various ruthenium(II) complexed rotaxanes, catenanes, scorpionates or macrocycles. In these compounds, one part of the system is set in motion by photochemically expelling a given chelate. We will discuss the behaviour of various topologically non-trivial systems like catenanes and rotaxanes as well as acyclic and macrocyclic models.
在过去几年中，人们精心构建了许多常被称为“分子机器”的动态系统。它们通常由化学、电化学或光化学反应等外部刺激驱动。光照射似乎特别有前景，因为输入信号可以在非常小的区域快速且容易地开启和关闭。在本教程综述中，我们将重点介绍各种钌（II）配合物轮烷、索烃、钳形配合物或大环化合物在设计与合成方面的最新进展。在这些化合物中，系统的一部分通过光化学方式排出特定螯合物而被驱动。我们将讨论各种拓扑结构不平凡的系统，如索烃和轮烷，以及非环状和大环模型的行为。
