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经处理的木材防腐剂与水生生物损害、人类疾病和死亡有关——一个社会问题。

Treated wood preservatives linked to aquatic damage, human illness, and death--a societal problem.

作者信息

Edlich Richard F, Winters Kathryne L, Long William B

机构信息

Plastic Surgery and Biomedical Engineering, University of Virginia Health System,Charlottesville, Virginia, USA.

出版信息

J Long Term Eff Med Implants. 2005;15(2):209-23. doi: 10.1615/jlongtermeffmedimplants.v15.i2.80.

Abstract

On February 12, 2002, the US Environmental Protection Agency (EPA) announced a voluntary decision by industry to move consumer use of treated lumber products away from a variety of pressure-treated wood that contains arsenate (As) by December 31, 2003, in favor of new alternative wood preservatives. Chromated copper arsenate (CCA) is a chemical mixture consisting of three pesticidal compounds (As, chromium, and copper) registered for wood preservative uses. CCA is injected into wood by a process that uses high pressure to saturate wood products with the chemical. Only people who have received the proper safety training should use CCA to treat wood products. Around the home, CCA-treated wood is commonly used for decks, walkways, fences, gazebos, boat docks, and playground equipment. Other common uses of CCA-treated wood include highway noise barriers, sign posts, utility posts, and retaining walls. As of January 1, 2004, the EPA is no longer allowing CCA products to be used to treat wood intended for any of these residential uses. This decision will facilitate the voluntary transition to new alternative wood preservatives that do not contain As in both the manufacturing and retail sectors. To its credit, the EPA has developed consumer safety information sheets, hanging signs, end signs, and bin stickers that provide comprehensive information about the dangers of CCA-treated wood, use-site, and handling precautions. The EPA has not concluded that CCA-treated wood poses any unreasonable risk to the public or the environment. Nevertheless, As is a known human carcinogen and, thus, the EPA believes that any reduction in the levels of potential exposure to As is desirable. The toxicologic manifestations have been primarily related to the effects of As exposure from drinking water sources and include the following: acute poisoning incidents, cardiovascular effects, diabetes mellitus, and cancer. Understanding the biomethylation of As is central to elucidating its action as a toxin and a carcinogen. In humans as in many other species, inorganic As is enzymatically converted to the methylated products methyl As (MAs) and dimethyl As (DMAs). The aforementioned voluntary agreement to reduce the uses of CCA-treated wood does not include a ban on the use of CCA for residential roofing. A major reason that this wood product should be banned from residential roofing is that it does not provide a Class "A" fire-rated roof system, which markedly reduce the frequency of residential roof fires.

摘要

2002年2月12日,美国环境保护局(EPA)宣布了一项行业自愿决定,即在2003年12月31日前,将消费者对经过处理的木材产品的使用,从含有砷酸盐(As)的各种加压处理木材转移至新的替代木材防腐剂。铬酸铜砷酸盐(CCA)是一种由三种注册用于木材防腐用途的杀虫化合物(As、铬和铜)组成的化学混合物。CCA通过一种利用高压使木材产品饱和该化学物质的工艺注入木材中。只有接受过适当安全培训的人员才能使用CCA处理木材产品。在家庭周围,经CCA处理的木材通常用于建造露台、人行道、围栏、凉亭、船坞和游乐场设备。经CCA处理的木材的其他常见用途包括公路隔音屏障、路标、电线杆和挡土墙。自2004年1月l日起,EPA不再允许使用CCA产品处理用于上述任何住宅用途的木材。这一决定将有助于在制造业和零售行业中自愿过渡到不含As的新替代木材防腐剂。值得称赞的是,EPA已制定了消费者安全信息表、悬挂标识、末端标识和垃圾桶贴纸,提供有关经CCA处理的木材的危险性、使用场所和处理预防措施的全面信息。EPA尚未得出经CCA处理的木材对公众或环境构成任何不合理风险的结论。然而,As是一种已知的人类致癌物,因此,EPA认为任何降低As潜在暴露水平的做法都是可取的。毒理学表现主要与饮用水源中As暴露的影响有关,包括以下方面:急性中毒事件、心血管影响、糖尿病和癌症。了解As的生物甲基化对于阐明其作为毒素和致癌物的作用至关重要。与许多其他物种一样,在人类中,无机As会通过酶促反应转化为甲基化产物甲基砷(MAs)和二甲基砷(DMAs)。上述减少经CCA处理木材使用的自愿协议并不包括禁止在住宅屋顶使用CCA。应禁止这种木材产品用于住宅屋顶的一个主要原因是,它不能提供“A”级防火屋顶系统,而这种系统能显著降低住宅屋顶火灾的发生率。

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