两性霉素3的C(1)-C(25)片段的合成：双烯丙基硼化反应在1,5-二醇合成中的应用
Synthesis of the C(1)-C(25) fragment of amphidinol 3: application of the double-allylboration reaction for synthesis of 1,5-diols.
作者信息
Flamme Eric M, Roush William R
机构信息
Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109-1055, USA.
出版信息
Org Lett. 2005 Mar 31;7(7):1411-4. doi: 10.1021/ol050250q.
PMID:15787519
Abstract
[structure: see text] A synthesis of the C(1)-C(25) fragment of amphidinol 3 is described. The synthesis features two applications of double allylboration reaction methodology for the highly stereoselective synthesis of 1,5-diol units in the C(1)-C(15) segment.
摘要
[结构：见正文] 描述了两性霉素3的C(1)-C(25)片段的合成。该合成的特点是两次应用双烯丙基硼化反应方法，用于在C(1)-C(15)片段中高度立体选择性地合成1,5-二醇单元。
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