2,4,6,8-四芳基-3,7-二氮杂双环[3.3.1]壬烷及其衍生物的合成与研究

Synthesis and study on 2,4,6,8-tetraaryl- 3,7-diazabicyclo[3.3.1]nonanes and their derivatives.

作者信息

Vijayakumar V, Sundaravadivelu M

机构信息

School of Chemical and Biotechnology, Shanmugha Arts, Science, Technology & Research Academy [SASTRA]-Deemed University, Thanjavur-613402, India.

出版信息

Magn Reson Chem. 2005 Jun;43(6):479-82. doi: 10.1002/mrc.1575.

DOI:10.1002/mrc.1575

PMID:15809985

Abstract

1-Carbethoxy-2,4,6,8-tetraaryl-3,7-diazabicyclo[3.3.1] nonan-9-ones (1, 2) were synthesized and their 1H and 13C NMR data are reported. Chemical shifts and spectral assignments for 2,4,6,8-tetrakis(4-chlorophenyl)-3,7-diazabicyclo[3.3.1]nonan-9-one (3), 2,4,6,8-tetraphenyl-3-thia-7-azabicyclo[3.3.1]nonan-9-one (4) and 2,4,6,8-tetraaryl-3,7-diazabicyclo[3.3.1]nonanes (5-7) are also included.

摘要

合成了1-羰基乙氧基-2,4,6,8-四芳基-3,7-二氮杂双环[3.3.1]壬烷-9-酮（1,2），并报道了它们的1H和13C NMR数据。还包括2,4,6,8-四（4-氯苯基）-3,7-二氮杂双环[3.3.1]壬烷-9-酮（3）、2,4,6,8-四苯基-3-硫杂-7-氮杂双环[3.3.1]壬烷-9-酮（4）和2,4,6,8-四芳基-3,7-二氮杂双环[3.3.1]壬烷（5-7）的化学位移和光谱归属。