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Square nets of tellurium: rare-earth dependent variation in the charge-density wave of RETe3 (RE = rare-earth element).

作者信息

Malliakas Christos, Billinge Simon J L, Kim Hyun Jeong, Kanatzidis Mercouri G

机构信息

Departments of Chemistry and Physics, Michigan State University, East Lansing, MI 48824, USA.

出版信息

J Am Chem Soc. 2005 May 11;127(18):6510-1. doi: 10.1021/ja0505292.

Abstract

The distortions in the square tellurium nets long known to exist in the structures of the charge-density wave materials, RETe3, have been elucidated. The (Te2)1- nets contain polytelluride oligomers which propagate in a fashion incommensurate from the adjacent (RETe)+ sublattice. The new information sets the stage for a much deeper understanding of these systems.

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