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镍二硫烯的光热漂白用于制备色彩鲜艳的三维打印零件。

Photothermal bleaching of nickel dithiolene for bright multi-colored 3D printed parts.

机构信息

HP Labs, 1501 Page Mill Road, Palo Alto, CA, 94304, USA.

出版信息

Nat Commun. 2023 Feb 3;14(1):586. doi: 10.1038/s41467-022-35195-4.

DOI:10.1038/s41467-022-35195-4
PMID:36737480
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9898272/
Abstract

HP's Multi Jet Fusion is a powder bed fusion 3D printing technology that utilizes a carbon-based radiation absorber in combination with a near infrared (NIR) light source to facilitate the fusion of polymer powder in a layer-by-layer fashion to generate 3D parts. Most available carbon-based and NIR radiation absorbers have an intrinsic dark color, which as a result will only produce black/gray and dark colored parts. However, there are many applications that require variable color, including prosthetics, medical models, and indicators, among others. To create white, bright colored, and translucent parts with MJF, a visibly transparent and colorless radiation absorber is required. In this paper, we designed an activating fusing agent (AFA) that contains a red, strong NIR absorbing dye that turns colorless after harvesting irradiation energy during the MJF 3D printing process and provide a bright colored part when working with other color agents.

摘要

惠普的多射流熔融技术是一种粉末床熔融 3D 打印技术,它利用基于碳的辐射吸收剂与近红外 (NIR) 光源相结合,以促进聚合物粉末在逐层方式中的融合,从而生成 3D 零件。大多数现有的基于碳的和 NIR 辐射吸收剂具有固有深色,因此只能产生黑色/灰色和深色零件。然而,有许多应用需要可变颜色,包括假肢、医学模型和指示器等。为了使用 MJF 制造白色、鲜艳的和半透明的零件,需要使用可见透明且无色的辐射吸收剂。在本文中,我们设计了一种激活融合剂 (AFA),它包含一种红色、强 NIR 吸收染料,在 MJF 3D 打印过程中吸收辐射能后会变成无色,并在与其他颜色剂一起使用时提供鲜艳的颜色零件。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6534/9898272/792b7ba8e14d/41467_2022_35195_Fig9_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6534/9898272/38b8c011f3a4/41467_2022_35195_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6534/9898272/dfc3caff3b1e/41467_2022_35195_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6534/9898272/26fe8188a1ec/41467_2022_35195_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6534/9898272/6937246910ec/41467_2022_35195_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6534/9898272/0e8beb7ab319/41467_2022_35195_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6534/9898272/fdcb322ad932/41467_2022_35195_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6534/9898272/84ade30f29d7/41467_2022_35195_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6534/9898272/f1681fbff2e4/41467_2022_35195_Fig8_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6534/9898272/792b7ba8e14d/41467_2022_35195_Fig9_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6534/9898272/38b8c011f3a4/41467_2022_35195_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6534/9898272/dfc3caff3b1e/41467_2022_35195_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6534/9898272/26fe8188a1ec/41467_2022_35195_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6534/9898272/6937246910ec/41467_2022_35195_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6534/9898272/0e8beb7ab319/41467_2022_35195_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6534/9898272/fdcb322ad932/41467_2022_35195_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6534/9898272/84ade30f29d7/41467_2022_35195_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6534/9898272/f1681fbff2e4/41467_2022_35195_Fig8_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6534/9898272/792b7ba8e14d/41467_2022_35195_Fig9_HTML.jpg

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Multi Jet Fusion PA12 Manufacturing Parameters for Watertightness, Strength and Tolerances.用于水密性、强度和公差的多射流熔融PA12制造参数
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White and Brightly Colored 3D Printing Based on Resonant Photothermal Sensitizers.
基于共振光热敏剂的白色和高亮度 3D 打印。
Nano Lett. 2018 Nov 14;18(11):6660-6664. doi: 10.1021/acs.nanolett.8b01164. Epub 2018 Jul 13.
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