Canac Yves, Conejero Salvador, Donnadieu Bruno, Schoeller Wolfgand W, Bertrand Guy
UCR-CNRS Joint Research Chemistry Laboratory (UMR 2282), Department of Chemistry, University of California, Riverside, 92521-0403, USA.
J Am Chem Soc. 2005 May 25;127(20):7312-3. doi: 10.1021/ja051109f.
(Amino)(silyl)carbenes, prepared by substitution reactions at a carbene center, can survive several days at 0 degrees C. These species are not push-pull carbenes as their phosphino analogues and therefore are excellent ligands for transition-metal centers.
通过卡宾中心的取代反应制备的（氨基）（硅基）卡宾，在0℃下可以存活数天。这些物种不像它们的膦类似物那样是推拉卡宾，因此是过渡金属中心的优良配体。
