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一种用于估算生物柴油生产成本的过程模型。

A process model to estimate biodiesel production costs.

作者信息

Haas Michael J, McAloon Andrew J, Yee Winnie C, Foglia Thomas A

机构信息

US Department of Agriculture, Agricultural Research Service, Eastern Regional Research Center, 600 East Mermaid Lane, Wyndmoor, PA 19038, USA.

出版信息

Bioresour Technol. 2006 Mar;97(4):671-8. doi: 10.1016/j.biortech.2005.03.039. Epub 2005 Jun 2.

DOI:10.1016/j.biortech.2005.03.039
PMID:15935657
Abstract

'Biodiesel' is the name given to a renewable diesel fuel that is produced from fats and oils. It consists of the simple alkyl esters of fatty acids, most typically the methyl esters. We have developed a computer model to estimate the capital and operating costs of a moderately-sized industrial biodiesel production facility. The major process operations in the plant were continuous-process vegetable oil transesterification, and ester and glycerol recovery. The model was designed using contemporary process simulation software, and current reagent, equipment and supply costs, following current production practices. Crude, degummed soybean oil was specified as the feedstock. Annual production capacity of the plant was set at 37,854,118 l (10 x 10(6)gal). Facility construction costs were calculated to be US dollar 11.3 million. The largest contributors to the equipment cost, accounting for nearly one third of expenditures, were storage tanks to contain a 25 day capacity of feedstock and product. At a value of US dollar 0.52/kg (dollar 0.236/lb) for feedstock soybean oil, a biodiesel production cost of US dollar 0.53/l (dollar 2.00/gal) was predicted. The single greatest contributor to this value was the cost of the oil feedstock, which accounted for 88% of total estimated production costs. An analysis of the dependence of production costs on the cost of the feedstock indicated a direct linear relationship between the two, with a change of US dollar 0.020/l (dollar 0.075/gal) in product cost per US dollar 0.022/kg (dollar 0.01/lb) change in oil cost. Process economics included the recovery of coproduct glycerol generated during biodiesel production, and its sale into the commercial glycerol market as an 80% w/w aqueous solution, which reduced production costs by approximately 6%. The production cost of biodiesel was found to vary inversely and linearly with variations in the market value of glycerol, increasing by US dollar 0.0022/l (dollar 0.0085/gal) for every US dollar 0.022/kg (dollar 0.01/lb) reduction in glycerol value. The model is flexible in that it can be modified to calculate the effects on capital and production costs of changes in feedstock cost, changes in the type of feedstock employed, changes in the value of the glycerol coproduct, and changes in process chemistry and technology.

摘要

“生物柴油”是一种由脂肪和油类生产的可再生柴油燃料的名称。它由脂肪酸的简单烷基酯组成,最常见的是甲酯。我们开发了一个计算机模型来估算一个中等规模的工业生物柴油生产设施的资本成本和运营成本。该工厂的主要工艺操作是连续工艺植物油酯交换反应以及酯和甘油的回收。该模型是使用当代工艺模拟软件,并按照当前生产实践,依据当前试剂、设备和供应成本设计的。指定粗制、脱胶大豆油为原料。该工厂的年生产能力设定为37,854,118升(10×10⁶加仑)。设施建设成本计算为1130万美元。设备成本的最大贡献者是储存罐,其容量为25天的原料和产品储存量,占支出的近三分之一。原料大豆油价格为0.52美元/千克(0.236美元/磅)时,预测生物柴油生产成本为0.53美元/升(2.00美元/加仑)。这一成本的最大单一贡献者是油原料成本,占估计总生产成本的88%。对生产成本与原料成本依赖性的分析表明,两者之间存在直接线性关系,油成本每变化0.022美元/千克(0.01美元/磅),产品成本变化0.020美元/升(0.075美元/加仑)。工艺经济性包括回收生物柴油生产过程中产生的副产物甘油,并将其作为80% w/w的水溶液销售到商业甘油市场,这使生产成本降低了约6%。发现生物柴油的生产成本与甘油的市场价值呈反比且线性变化,甘油价值每降低0.022美元/千克(0.01美元/磅),生产成本增加0.0022美元/升(0.0085美元/加仑)。该模型具有灵活性,因为它可以修改以计算原料成本变化、所用原料类型变化、甘油副产物价值变化以及工艺化学和技术变化对资本成本和生产成本的影响。

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