银（I）氮杂环卡宾配合物在催化制备1,2-双（硼酸酯）酯中的前所未有的应用。
Unprecedented use of silver(I) N-heterocyclic carbene complexes for the catalytic preparation of 1,2-bis(boronate) esters.
作者信息
Ramírez Jesus, Corberán Rosa, Sanaú Mercedes, Peris Eduardo, Fernandez Elena
机构信息
Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, Pça. Imperial Tàrraco 1, 43005, Tarragona, Spain.
出版信息
Chem Commun (Camb). 2005 Jun 28(24):3056-8. doi: 10.1039/b503239c. Epub 2005 May 6.
DOI:10.1039/b503239c
PMID:15959583
Abstract
Catalytic diboration of internal and terminal alkenes with Ag(I) N-heterocyclic carbene complexes leads to 1,2-bis(boronate) esters as single intermediates, that can be oxidised towards the corresponding diols.
摘要
使用银（I）氮杂环卡宾配合物对内部烯烃和末端烯烃进行催化双硼化反应可生成1,2 - 双（硼酸酯）酯作为单一中间体，该中间体可被氧化为相应的二醇。
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