Department of Chemistry, Merkert Chemistry Center , Boston College , Chestnut Hill , Massachusetts 02467 , United States.
J Am Chem Soc. 2018 Mar 14;140(10):3663-3673. doi: 10.1021/jacs.7b12316. Epub 2018 Mar 2.
A mechanistic investigation of the carbohydrate/DBU cocatalyzed enantioselective diboration of alkenes is presented. These studies provide an understanding of the origin of stereoselectivity and also reveal a strategy for enhancing reactivity and broadening the substrate scope.
本文对碳水化合物/DBU 共催化烯烃的对映选择性双硼化反应进行了机理研究。这些研究提供了对立体选择性起源的理解,也揭示了一种提高反应性和拓宽底物范围的策略。