Pandey Jitendra K, Kumar A Pratheep, Misra Manjusri, Mohanty Amar K, Drzal Lawrence T, Singh Raj Pal
Polymer Chemistry Division, National Chemical Laboratory, Pune-411008, India.
J Nanosci Nanotechnol. 2005 Apr;5(4):497-526. doi: 10.1166/jnn.2005.111.
There is growing interest in developing bio-based products and innovative process technologies that can reduce the dependence on fossil fuel and move to a sustainable materials basis. Biodegradable bio-based nanocomposites are the next generation of materials for the future. Renewable resource-based biodegradable polymers including cellulosic plastic (plastic made from wood), corn-derived plastics, and polyhydroxyalkanoates (plastics made from bacterial sources) are some of the potential biopolymers which, in combination with nanoclay reinforcement, can produce nanocomposites for a variety of applications. Nanocomposites of this category are expected to possess improved strength and stiffness with little sacrifice of toughness, reduced gas/water vapor permeability, a lower coefficient of thermal expansion, and an increased heat deflection temperature, opening an opportunity for the use of new, high performance, lightweight green nanocomposite materials to replace conventional petroleum-based composites. The present review addresses this green material, including its technical difficulties and their solutions.
开发能够减少对化石燃料的依赖并转向可持续材料基础的生物基产品和创新工艺技术,正引发越来越多的关注。可生物降解的生物基纳米复合材料是未来的下一代材料。基于可再生资源的可生物降解聚合物,包括纤维素塑料(由木材制成的塑料)、玉米衍生塑料和聚羟基脂肪酸酯(由细菌来源制成的塑料),是一些潜在的生物聚合物,它们与纳米粘土增强材料相结合,可以生产用于各种应用的纳米复合材料。预计这类纳米复合材料在韧性牺牲很小的情况下具有更高的强度和刚度,降低气体/水蒸气渗透性,降低热膨胀系数,并提高热变形温度,这为使用新型、高性能、轻质的绿色纳米复合材料取代传统的石油基复合材料提供了机会。本综述讨论了这种绿色材料,包括其技术难题及其解决方案。