碘化亚铜催化的羰基化合物分子内O-乙烯基化反应。
CuI-catalyzed intramolecular O-vinylation of carbonyl compounds.
作者信息
Fang Yewen, Li Chaozhong
机构信息
Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, PR China.
出版信息
Chem Commun (Camb). 2005 Jul 28(28):3574-6. doi: 10.1039/b505006e. Epub 2005 Jun 1.
DOI:10.1039/b505006e
PMID:16010328
Abstract
The first copper-catalyzed intramolecular O-vinylation of carbonyl compounds with vinyl bromides was reported, among which the efficient formation of 5-, 6- and even 7-membered cyclic alkenyl ethers was achieved with beta-ketoesters as nucleophiles.
摘要
首次报道了铜催化的羰基化合物与乙烯基溴的分子内O-乙烯基化反应，其中以β-酮酯作为亲核试剂高效地生成了5元、6元甚至7元环状烯基醚。
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