Appelt Stephan, Häsing F Wolfgang, Kühn Holger, Perlo Juan, Blümich Bernhard
Zentralinstitut für Elektronik, Forschungszentrum Jülich, Germany.
Phys Rev Lett. 2005 May 20;94(19):197602. doi: 10.1103/PhysRevLett.94.197602. Epub 2005 May 17.
Conventional high resolution nuclear magnetic resonance (NMR) spectra are usually measured in homogeneous, high magnetic fields (>1 T), which are produced by expensive and immobile superconducting magnets. We show that chemically resolved xenon (Xe) NMR spectroscopy of liquid samples can be measured in the Earth's magnetic field (5 x 10(-5) T) with a continuous flow of hyperpolarized Xe gas. It was found that the measured normalized Xe frequency shifts are significantly modified by the Xe polarization density, which causes different dipolar magnetic fields in the liquid and in the gas phases.
传统的高分辨率核磁共振(NMR)光谱通常在均匀的高磁场(>1 T)中测量,这种高磁场由昂贵且固定的超导磁体产生。我们表明,通过连续流动超极化氙气,可以在地球磁场(5×10⁻⁵ T)中对液体样品进行化学分辨的氙(Xe)NMR光谱测量。研究发现,所测量的归一化Xe频率偏移会因Xe极化密度而发生显著改变,这会在液相和气相中产生不同的偶极磁场。