连续糖基化策略中的硫代糖苷。
Thioglycosides in sequential glycosylation strategies.
作者信息
Codée Jeroen D C, Litjens Remy E J N, van den Bos Leendert J, Overkleeft Herman S, van der Marel Gijsbert A
机构信息
Leiden Institute of Chemistry, Leiden University, P. O. Box 9502, 2300 RA Leiden, The Netherlands.
出版信息
Chem Soc Rev. 2005 Sep;34(9):769-82. doi: 10.1039/b417138c. Epub 2005 Jul 27.
DOI:10.1039/b417138c
PMID:16100617
Abstract
This tutorial review surveys the use of thioglycosides in the development of sequential glycosylation methodologies, with a focus on chemoselective, orthogonal and iterative glycosylation strategies reported since the beginning of this century. Both fundamental aspects of glycosidic bond formation and ingenious state-of-the-art methodologies are presented.
摘要
本教程综述了硫代糖苷在连续糖基化方法开发中的应用，重点关注本世纪初以来报道的化学选择性、正交和迭代糖基化策略。文中既介绍了糖苷键形成的基本方面，也展示了巧妙的前沿方法。
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