A remarkably effective catalyst for the asymmetric transfer hydrogenation of aromatic ketones in water and air.
作者信息
Wu Xiaofeng, Vinci Daniele, Ikariya Takao, Xiao Jiangliang
机构信息
Liverpool Centre for Materials and Catalysis, Department of Chemistry, University of Liverpool, Liverpool, UKL69 7ZD.
出版信息
Chem Commun (Camb). 2005 Sep 21(35):4447-9. doi: 10.1039/b507276j. Epub 2005 Jul 29.
DOI:10.1039/b507276j
PMID:16136246
Abstract
A Rh(III) complex generated in situ from [Cp*RhCl2]2 and (1R,2R)-N-(p-toluenesulfonyl)-1,2-cyclohexanediamine (TsCYDN) serves as a remarkably effective, robust catalyst for the asymmetric transfer hydrogenation of aromatic ketones by HCOONa in water in air, affording alcohols in up to 99% ee.
摘要
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