富勒烯金属化物Sc3C82的结构测定再探：一个惊人的发现。
Structural determination of metallofullerene Sc3C82 revisited: a surprising finding.
作者信息
Iiduka Yuko, Wakahara Takatsugu, Nakahodo Tsukasa, Tsuchiya Takahiro, Sakuraba Akihiro, Maeda Yutaka, Akasaka Takeshi, Yoza Kenji, Horn Ernst, Kato Tatsuhisa, Liu Michael T H, Mizorogi Naomi, Kobayashi Kaoru, Nagase Shigeru
机构信息
Center for Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan.
出版信息
J Am Chem Soc. 2005 Sep 14;127(36):12500-1. doi: 10.1021/ja054209u.
PMID:16144392
Abstract
We report here the structural determination of the Sc3C82 molecule by 13C NMR spectroscopy and X-ray single-crystal structure analysis. From the present study, it is obvious that the structure of Sc3C82 is not Sc3@C82 but Sc3C2@C80.
摘要
我们在此报告通过¹³C核磁共振光谱和X射线单晶结构分析对Sc₃C₈₂分子的结构测定。从本研究中可以明显看出，Sc₃C₈₂的结构不是Sc₃@C₈₂，而是Sc₃C₂@C₈₀。
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