Guo Hao, Qian Rong, Liao Yuanxi, Ma Shengming, Guo Yinlong
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, P R China.
J Am Chem Soc. 2005 Sep 21;127(37):13060-4. doi: 10.1021/ja052588l.
Four cationic palladium intermediates have been characterized by the high-resolution ESI-FTMS technology, on the basis of which a mechanism was proposed for the Pd0-catalyzed three-component tandem double addition cyclization of organic halides, 2-(2,3-allenyl)malonates, and imines.
通过高分辨率电喷雾傅里叶变换离子回旋共振质谱技术对四种阳离子钯中间体进行了表征，在此基础上提出了一种关于零价钯催化有机卤化物、2-(2,3-联烯基)丙二酸酯和亚胺的三组分串联双加成环化反应的机理。
