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取代基对芳基C-H...阴离子氢键强度的影响。

Influence of substituents on the strength of aryl C-H...anion hydrogen bonds.

作者信息

Bryantsev Vyacheslav S, Hay Benjamin P

机构信息

Chemical Science Division, Pacific Northwest National Laboratory, Richland, Washington 99352, USA.

出版信息

Org Lett. 2005 Oct 27;7(22):5031-4. doi: 10.1021/ol0520119.

DOI:10.1021/ol0520119
PMID:16235950
Abstract

[structure: see text]When electron-withdrawing substituents are present, aryl C-H groups become powerful hydrogen bond donors, forming stronger complexes than obtained with conventional O-H and N-H groups.

摘要

[结构：见正文]当存在吸电子取代基时，芳基C-H基团成为强大的氢键供体，形成比传统O-H和N-H基团更强的配合物。

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