Apostoluk Wiesław, Drzymała Jan
Wrocław University of Technology, Wybrzeze Wyspiańskiego 27, 50-370 Wrocław, Poland.
J Colloid Interface Sci. 2003 Jun 15;262(2):483-8. doi: 10.1016/S0021-9797(03)00115-2.
An equation based on the linear solvation energy relationship (LSER) was proposed to predict the interfacial tension between organic liquid and water. The equation takes into account five parameters characterizing properties of the organic liquid molecule: excess molar refraction, solute dipolarity/polarizability, effective hydrogen bond acidity, effective hydrogen bond basicity, and the McGowan molar intrinsic volume. The proposed equation provides a better approximation of the interfacial tension than a similar one derived earlier by Freitas et al. (J. Phys. Chem. B 101 (1997, 7488-7493), which is based on seven terms.
提出了一个基于线性溶剂化能关系（LSER）的方程来预测有机液体与水之间的界面张力。该方程考虑了表征有机液体分子性质的五个参数：过量摩尔折射度、溶质偶极矩/极化率、有效氢键酸度、有效氢键碱度以及麦高恩摩尔固有体积。与Freitas等人（《物理化学杂志B》101卷，（1997年，7488 - 7493页））早期推导的基于七个项的类似方程相比，所提出的方程能更好地近似界面张力。
