di Lena Fabio, Quintanilla Esther, Chen Peter
Laboratorium für Organische Chemie, ETH Zürich, Switzerland.
Chem Commun (Camb). 2005 Dec 14(46):5757-9. doi: 10.1039/b511997a. Epub 2005 Oct 21.
Electrospray ionization mass spectrometry (ESI-MS) of MAO-activated metallocene-catalyzed polymerizations quenched with carbodiimides provides a method for the determination of rate constants in Ziegler-Natta polymerizations.
用碳二亚胺猝灭茂金属催化的由单活性中心催化剂引发的聚合反应后,通过电喷雾电离质谱(ESI-MS)测定,可以得到在齐格勒-纳塔聚合反应中速率常数的方法。