硝单胞菌属氨单加氧酶与烷烃、烯烃和炔烃的相互作用。
Interaction of Ammonia Monooxygenase from Nitrosomonas europaea with Alkanes, Alkenes, and Alkynes.
机构信息
Department of Biochemistry, University of California, Riverside, California 92521.
出版信息
Appl Environ Microbiol. 1988 Dec;54(12):3187-90. doi: 10.1128/aem.54.12.3187-3190.1988.
Abstract
Ammonia monooxygenase of Nitrosomonas europaea catalyzes the oxidation of alkanes (up to C(8)) to alcohols and alkenes (up to C(5)) to epoxides and alcohols in the presence of ammonium ions. Straight-chain, N-terminal alkynes (up to C(10)) all exhibited a time-dependent inhibition of ammonia oxidation without effects on hydrazine oxidation.
摘要
欧洲亚硝化单胞菌的氨单加氧酶能够在氨离子存在的条件下，将烷烃（最高至 C(8)）氧化为醇和烯烃（最高至 C(5)），将环氧化物和醇氧化为环氧化物和醇。直链、N 端炔烃（最高至 C(10)）均表现出时间依赖性的氨氧化抑制作用，而对肼氧化无影响。
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