粘帚霉 T(2)对长叶烯的分子重排。
Molecular Rearrangement of Longifolene by Arthrobacter ilicis T(2).
机构信息
Department of Microbiology and Department of Chemistry, Goa University, Taleigao Plateau, Goa 403 203, India.
出版信息
Appl Environ Microbiol. 1993 May;59(5):1691-3. doi: 10.1128/aem.59.5.1691-1693.1993.
Abstract
Arthrobacter ilicis T(2) brings about a unique type of cometabolic structural rearrangement of longifolene, a sesquiterpene, resulting in the formation of an acid. Infrared, nuclear magnetic resonance, mass spectrometry, and decoupling studies indicate that the acid product has a sativenelike structure, which is confirmed by conversion of the acid to its methyl ester and hydrocarbon.
摘要
节杆菌属（Arthrobacter）ilicis T(2) 可使长叶烯（一种倍半萜烯）发生独特的共代谢结构重排，生成一种酸。红外、核磁共振、质谱和去耦研究表明，该酸产物具有类似葎草烯的结构，这一结构通过将酸转化为甲酯和烃类化合物得到了证实。
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