一种从D-葡萄糖高效合成D-赤藓糖型和D-苏阿糖型鞘氨醇的方法：烯烃复分解法。
An efficient synthesis of D-erythro- and D-threo-sphingosine from D-glucose: olefin cross-metathesis approach.
作者信息
Chaudhari Vinod D, Kumar K S Ajish, Dhavale Dilip D
机构信息
Department of Chemistry, Garware Research Centre, University of Pune, Pune-411 007, India.
出版信息
Org Lett. 2005 Dec 22;7(26):5805-7. doi: 10.1021/ol052320z.
PMID:16354071
Abstract
[reaction: see text] The D-erythro- and D-threo-sphingosine were synthesized via E-selective olefin cross-metathesis using a D-glucose-derived building block and long-chain terminal alkene.
摘要
[反应：见正文] 通过使用D-葡萄糖衍生的结构单元和长链末端烯烃，经由E-选择性烯烃交叉复分解反应合成了D-赤藓型和D-苏阿糖型鞘氨醇。
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