Chaudhari Vinod D, Kumar K S Ajish, Dhavale Dilip D
Department of Chemistry, Garware Research Centre, University of Pune, Pune-411 007, India.
Org Lett. 2005 Dec 22;7(26):5805-7. doi: 10.1021/ol052320z.
[reaction: see text] The D-erythro- and D-threo-sphingosine were synthesized via E-selective olefin cross-metathesis using a D-glucose-derived building block and long-chain terminal alkene.
[反应:见正文] 通过使用D-葡萄糖衍生的结构单元和长链末端烯烃,经由E-选择性烯烃交叉复分解反应合成了D-赤藓型和D-苏阿糖型鞘氨醇。