异戊烯基萘醌的周环反应：莫洛苷和小叶醌的仿生合成
Pericyclic reactions of prenylated naphthoquinones: biomimetic syntheses of mollugin and microphyllaquinone.
作者信息
Lumb Jean-Philip, Trauner Dirk
机构信息
Department of Chemistry, University of California, Berkeley, California 94720, USA.
出版信息
Org Lett. 2005 Dec 22;7(26):5865-8. doi: 10.1021/ol052472u.
PMID:16354086
Abstract
[reaction: see text] A total synthesis of the bioactive naphthohydroquinone mollugin and the related naphthoquinone dimer microphyllaquinone is described. Both syntheses exploit the propensity of prenylated quinones to undergo tautomerization/oxa 6pi-electrocyclizations.
摘要
[反应：见正文] 本文描述了具有生物活性的萘氢醌莫卢金和相关萘醌二聚体小叶醌的全合成。两种合成方法都利用了异戊烯基化醌发生互变异构/氧杂6π-电环化反应的倾向。
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