Lumb Jean-Philip, Trauner Dirk
Department of Chemistry, University of California, Berkeley, California 94720, USA.
Org Lett. 2005 Dec 22;7(26):5865-8. doi: 10.1021/ol052472u.
[reaction: see text] A total synthesis of the bioactive naphthohydroquinone mollugin and the related naphthoquinone dimer microphyllaquinone is described. Both syntheses exploit the propensity of prenylated quinones to undergo tautomerization/oxa 6pi-electrocyclizations.
[反应：见正文] 本文描述了具有生物活性的萘氢醌莫卢金和相关萘醌二聚体小叶醌的全合成。两种合成方法都利用了异戊烯基化醌发生互变异构/氧杂6π-电环化反应的倾向。
