Prudente Frederico V, Costa Luis S, Vianna José David M
Instituto de Física, Universidade Federal da Bahia, 40210-340 Salvador-Bahia, Brazil.
J Chem Phys. 2005 Dec 8;123(22):224701. doi: 10.1063/1.2131068.
A variational method called discrete variable representation is applied to study the energy spectra of two interacting electrons in a quantum dot with a three-dimensional anisotropic harmonic confinement potential. This method, applied originally to problems in molecular physics and theoretical chemistry, is here used to solve the eigenvalue equation to relative motion between the electrons. The two-electron quantum dot spectrum is determined then with a precision of at least six digits. Moreover, the electron correlation energies for various potential confinement parameters are investigated for singlet and triplet states. When possible, the present results are compared with the available theoretical values.