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带电圆柱体上的抗衡离子:超越平均场理论的临界性和普遍性

Counterions at charged cylinders: criticality and universality beyond mean-field theory.

作者信息

Naji Ali, Netz Roland R

机构信息

Physics Department, Technical University of Munich, 85748 Garching, Germany.

出版信息

Phys Rev Lett. 2005 Oct 28;95(18):185703. doi: 10.1103/PhysRevLett.95.185703. Epub 2005 Oct 27.

Abstract

The counterion-condensation transition at charged cylinders is studied using Monte Carlo simulations. Employing logarithmically rescaled radial coordinates, large system sizes are tractable and the critical behavior is determined by a combined finite-size and finite-ion-number analysis. Critical counterion localization exponents are introduced and found to be in accord with mean-field theory both in two (2D) and three (3D) dimensions. In 3D, the heat capacity shows a universal jump at the transition, while in 2D, it consists of discrete peaks where single counterions successively condense.

摘要

利用蒙特卡罗模拟研究了带电圆柱上的反离子凝聚转变。采用对数重标径向坐标,大系统规模变得易于处理,并且通过有限尺寸和有限离子数的联合分析确定了临界行为。引入了临界反离子局域化指数,发现其在二维(2D)和三维(3D)中均与平均场理论一致。在三维中,热容量在转变处呈现出普遍的跳跃,而在二维中,它由单个反离子相继凝聚的离散峰组成。

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