邻联苯胍基苯 - 苯甲酸配合物的绝对有序簇形成。
Absolute ordered cluster formation of an o-bisguanidinobenzene-benzoic acid complexes.
作者信息
Kawahata Masatoshi, Shikii Kazuaki, Seki Hiroko, Ishikawa Tsutomu, Yamaguchi Kentaro
机构信息
Faculity of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, Shido, Sanuki, Japan.
出版信息
Chem Pharm Bull (Tokyo). 2006 Jan;54(1):147-8. doi: 10.1248/cpb.54.147.
PMID:16394572
Abstract
Stoichiometry-controlled complexation of o-phenylenebis-(N,N'-dimethyl-N,N'-ethylene)guanidine (BG) and benzoic acid (BA), which is forming 1:1, 1:2, 1:3, and 1:4 BG+BA systems, was observed in solution by using cold-spray ionization mass spectrometry CSI-MS and pulsed field gradient PFG NMR diffusion and in the solid state by X-ray structure analysis.
摘要
通过冷喷雾电离质谱（CSI-MS）和脉冲场梯度（PFG）核磁共振扩散在溶液中以及通过X射线结构分析在固态下观察到邻亚苯基双（N，N'-二甲基-N，N'-亚乙基）胍（BG）与苯甲酸（BA）的化学计量控制络合，形成了1:1、1:2、1:3和1:4的BG+BA体系。
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