基于DNA的高度对映选择性催化。
Highly enantioselective DNA-based catalysis.
作者信息
Roelfes Gerard, Boersma Arnold J, Feringa Ben L
机构信息
Department of Organic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, Groningen, The Netherlands.
出版信息
Chem Commun (Camb). 2006 Feb 14(6):635-7. doi: 10.1039/b516552k. Epub 2006 Jan 6.
DOI:10.1039/b516552k
PMID:16446834
Abstract
A new approach to DNA-based asymmetric catalysis is presented, which gives rise to very high enantioselectivities (up to 99% ee) in the copper catalyzed Diels-Alder reaction in water.
摘要
本文提出了一种基于DNA的不对称催化新方法，该方法在水中铜催化的狄尔斯-阿尔德反应中产生了非常高的对映选择性（高达99% ee）。
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