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可食用的地中海甲壳类动物普通岩龙虾(多刺龙虾)肌肉和头胸部中的主要磷脂及其脂肪酸组成。

Main phospholipids and their fatty acid composition in muscle and cephalothorax of the edible Mediterranean crustacean Palinurus vulgaris (spiny lobster).

作者信息

Garofalaki Theodosia F, Miniadis-Meimaroglou Sofia, Sinanoglou Vassilia J

机构信息

Food Chemistry Laboratory, Department of Chemistry, University of Athens, Greece.

出版信息

Chem Phys Lipids. 2006 Apr;140(1-2):55-65. doi: 10.1016/j.chemphyslip.2006.01.006. Epub 2006 Feb 7.

DOI:10.1016/j.chemphyslip.2006.01.006
PMID:16488404
Abstract

The total lipids of muscle and cephalothorax of Mediterranean lobster Palinurus vulgaris were found to be 1.0% and 2.4% of the wet tissue of which the phospholipids represented 66.5% and 47.5%, respectively. The main PhL saturated, monounsaturated and polyunsaturated fatty acids in muscle and cephalothorax were C16:0, C18:0, C18:1omega-9, C18:1omega-7, C20:4omega-6, C20:5omega-3 and C22:6omega-3. 2-OH C14:0 and cyclo-17:0 fatty acids were also identified though in low percentages. The main individual PhL in muscle were found to be phosphatidylcholine (53.5%), 72.0% of which corresponded to the structure of 1,2-diacyl-glycerocholine while the rest 28.0% to 1-O-alkyl-2-acyl-glycerocholine or 1-O-(1-alkenyl)-2-acyl-glycerocholine and phosphatidylethanolamine (19.3%), 75.0% of which corresponded to the structure of 1,2-diacyl-glyceroethanolamine and 25% to 1-O-alkyl-2-acyl-glyceroethanolamine or 1-O-(1-alkenyl)-2-acyl-glyceroethanolamine. Cephalothorax main PhL were found to be PC and PE (66.4% and 18.8%, respectively). In muscle and cephalothorax PC omega-3 fatty acids amounted 7.78% and 8.60%, while in PE amounted 30.77% and 23.65% respectively. Furthermore, in both tissues PhL, cardiolipine phosphatidylserine, phosphatidylinositol, sphingomyelin and lysophosphatidylcholine, were also found.

摘要

研究发现,地中海龙虾(Palinurus vulgaris)肌肉和头胸部的总脂质分别占湿组织的1.0%和2.4%,其中磷脂分别占66.5%和47.5%。肌肉和头胸部中主要的磷脂饱和脂肪酸、单不饱和脂肪酸和多不饱和脂肪酸分别为C16:0、C18:0、C18:1ω-9、C18:1ω-7、C20:4ω-6、C20:5ω-3和C22:6ω-3。虽然2-OH C14:0和环-17:0脂肪酸的含量较低,但也被鉴定出来。肌肉中主要的磷脂个体被发现是磷脂酰胆碱(53.5%),其中72.0%对应1,2-二酰基甘油胆碱的结构,其余28.0%对应1-O-烷基-2-酰基甘油胆碱或1-O-(1-烯基)-2-酰基甘油胆碱;以及磷脂酰乙醇胺(19.3%),其中75.0%对应1,2-二酰基甘油乙醇胺的结构,25%对应1-O-烷基-2-酰基甘油乙醇胺或1-O-(1-烯基)-2-酰基甘油乙醇胺。头胸部主要的磷脂是PC和PE(分别为66.4%和18.8%)。在肌肉和头胸部中,PC中的ω-3脂肪酸含量分别为7.78%和8.60%,而在PE中分别为30.77%和23.65%。此外,在这两种组织的磷脂中,还发现了心磷脂、磷脂酰丝氨酸、磷脂酰肌醇、鞘磷脂和溶血磷脂酰胆碱。

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