日本龙虾（Panulirus japonicus）中的类胡萝卜素及其脂肪酸酯。

Carotenoids and their fatty acid esters of spiny lobster Panulirus japonicus.

作者信息

Maoka Takashi, Akimoto Naoshige

机构信息

Research Institute for Production Development, Kyoto, Japan.

出版信息

J Oleo Sci. 2008;57(3):145-52. doi: 10.5650/jos.57.145.

DOI:10.5650/jos.57.145

PMID:18270463

Abstract

Carotenoids and their fatty acid esters in the carapace of the spiny lobster Panulirus japonicus were investigated. Fatty acid esters of astaxanthin, adonixanthin, and pectenolone were characterized by (1)H-NMR and FAB-MS. The acylated position of adonixanthin and pectenolone monoesters was determined to be a hydroxy group at C-3' by (1)H-NMR. The fatty acids esterified with these carotenoids were identified as C22:6, C20:4, C20:5, C18:0, C18:1, C17:0, C16:0, C16:1, C14:0, and C12:0 from FAB-MS spectral data. Furthermore, 2,3-didehydrocanthaxanthin (4) was first identified as a natural product.

摘要

对日本龙虾（Panulirus japonicus）头胸甲中的类胡萝卜素及其脂肪酸酯进行了研究。通过¹H-NMR和FAB-MS对虾青素、阿多尼黄质和扇贝酮的脂肪酸酯进行了表征。通过¹H-NMR确定阿多尼黄质和扇贝酮单酯的酰化位置为C-3'处的羟基。根据FAB-MS光谱数据，鉴定出与这些类胡萝卜素酯化的脂肪酸为C22:6、C20:4、C20:5、C18:0、C18:1、C17:0、C16:0、C16:1、C14:0和C12:0。此外，首次将2,3-去氢角黄素（4）鉴定为天然产物。