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Planar chiral cyclic amine and its derivatives: synthesis and stereochemical behavior.

作者信息

Tomooka Katsuhiko, Suzuki Masaki, Shimada Maki, Yanagitsuru Syun-ichi, Uehara Kazuhiro

机构信息

Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, Meguro-ku, Tokyo 152-8552, Japan.

出版信息

Org Lett. 2006 Mar 2;8(5):963-5. doi: 10.1021/ol053141k.

DOI:10.1021/ol053141k
PMID:16494485
Abstract

Nine-membered diallylic cyclic amines and amides have remarkably stable planar chirality. The transformation of enantiomerically enriched amides provides optically active nitrogen heterocycles containing stereogenic centers in a stereospecific fashion.

摘要

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