α-烷基乙烯基芳烃的高度对映选择性氢乙烯基化反应：构建全碳季碳立体中心的一种方法。
Highly enantioselective hydrovinylation of alpha-alkyl vinylarenes. an approach to the construction of all-carbon quaternary stereocenters.
作者信息
Shi Wen-Jian, Zhang Qi, Xie Jian-Hua, Zhu Shou-Fei, Hou Guo-Hua, Zhou Qi-Lin
机构信息
State Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071, China.
出版信息
J Am Chem Soc. 2006 Mar 8;128(9):2780-1. doi: 10.1021/ja057654y.
PMID:16506739
Abstract
The highly enantioselective hydrovinylation of alpha-alkyl vinylarenes was realized by using nickel complexes of chiral spiro phosphoramidite ligands. The method provided a new approach to the construction of chiral all-carbon quaternary centers.
摘要
通过使用手性螺环亚磷酰胺配体的镍配合物，实现了α-烷基乙烯基芳烃的高度对映选择性氢乙烯基化反应。该方法为构建手性全碳季碳中心提供了一种新途径。
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