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一个配位π-π框架表现出自发磁化。

A coordination pi-pi framework exhibits spontaneous magnetization.

作者信息

Li Lu-Lin, Lin Kuan-Jiuh, Ho Chin-Jun, Sun Chia-Pin, Yang Hung-Duen

机构信息

Department of Chemistry, Center of Nanoscience and Nanotechnology, National Chung-Hsing University, Taichung 402, Taiwan (Republic of China).

出版信息

Chem Commun (Camb). 2006 Mar 28(12):1286-8. doi: 10.1039/b515681e. Epub 2006 Feb 10.

DOI:10.1039/b515681e
PMID:16538249
Abstract

A pi-pi scaffolding framework that was assembled as a one-dimensional chain structure comprising alternating Delta- and Lambda-iron(II) chiral building units, [Fe(II)(Delta)Fe(II)(Lambda)(ox)2(phen)2]n, reveals spontaneous magnetization that gives rise to pronounced hysteresis loops below 10 K.

摘要

一种π-π支架框架,它被组装成一维链状结构,由交替的Δ-和Λ-铁(II)手性构建单元[Fe(II)(Δ)Fe(II)(Λ)(ox)2(phen)2]n组成,显示出自发磁化,在10 K以下产生明显的磁滞回线。

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