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链状聚[[(2,2'-联吡啶-κN,N')镍(II)]-μ-草酸根-κO,O:O,O]

catena-Poly[[(2,2'-bipyridine-κN,N')nickel(II)]-μ-oxalato-κO,O:O,O].

作者信息

Li Sheng, Yan Xing-Lian, Wang Shou-Bin, Ma Yuan-Fang

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 13;64(Pt 10):m1258. doi: 10.1107/S1600536808028389.

DOI:10.1107/S1600536808028389
PMID:21201013
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2959270/
Abstract

The title compound, Ni(C(2)O(4))(C(10)H(8)N(2)), is isostructural with its Mn(II), Fe(II), Cu(II) and Zn(II) analogues. Each Ni(II) atom is chelated by two oxalate ligands and one 2,2'-bipyridine, forming a slightly distorted octa-hedral geometry. Oxlate acts as a bridge to link neighbouring pairs of Ni(II) cations, forming a one-dimensional wave-like chain. The crystal showed partial inversion twinning.

摘要

标题化合物[Ni(C₂O₄)(C₁₀H₈N₂)]ₙ与其锰(II)、铁(II)、铜(II)和锌(II)的类似物同构。每个镍(II)原子由两个草酸根配体和一个2,2'-联吡啶螯合，形成略微扭曲的八面体几何构型。草酸根作为桥连接相邻的镍(II)阳离子对，形成一维波浪状链。该晶体表现出部分倒转孪晶。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c638/2959270/cfbe867c9479/e-64-m1258-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c638/2959270/05fb6d31214a/e-64-m1258-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c638/2959270/cfbe867c9479/e-64-m1258-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c638/2959270/05fb6d31214a/e-64-m1258-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c638/2959270/cfbe867c9479/e-64-m1258-fig2.jpg

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