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1,3,5-三氮杂-7-磷杂金刚烷（PTA）的锰配合物：首个氮配位的PTA过渡金属配合物

Manganese complexes of 1,3,5-triaza-7-phosphaadamantane (PTA): the first nitrogen-bound transition-metal complex of PTA.

作者信息

Frost Brian J, Bautista Carolyn M, Huang Rongcai, Shearer Jason

机构信息

Department of Chemistry, MS 216, University of Nevada, Reno, Nevada 89557, USA.

出版信息

Inorg Chem. 2006 May 1;45(9):3481-3. doi: 10.1021/ic060322p.

DOI:10.1021/ic060322p
PMID:16634574
Abstract

The structures of two manganese(II) complexes of 1,3,5-triaza-7-phosphaadamantane (PTA) reveal the first transition-metal complexes of PTA in which the metal preferentially coordinates to a nitrogen and not the phosphorus of PTA. The coordination environment about the manganese was probed using X-ray crystallography (solid state) and EXAFS spectroscopy (solution).

摘要

1,3,5-三氮杂-7-磷杂金刚烷（PTA）的两种锰（II）配合物的结构揭示了PTA的首批过渡金属配合物，其中金属优先与PTA的氮而非磷配位。使用X射线晶体学（固态）和EXAFS光谱（溶液）对锰周围的配位环境进行了探究。

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