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将1,3,5-三氮杂-7-磷杂金刚烷(PTA)的配位化学扩展至钴中心:共PTA配合物以及含PTA氧化物配体的金属配合物的首例。

Extending the coordination chemistry of 1,3,5-triaza-7-phosphaadamantane (PTA) to cobalt centers: first examples of co-PTA complexes and of a metal complex with the PTA oxide ligand.

作者信息

Jaremko Lukasz, Kirillov Alexander M, Smoleński Piotr, Lis Tadeusz, Pombeiro Armando J L

机构信息

Centro Química Estrutural, Complexo I, Instituto Superior Técnico, TU Lisbon, Avenida Rovisco Pais, 1049-001 Lisbon, Portugal.

出版信息

Inorg Chem. 2008 Apr 21;47(8):2922-4. doi: 10.1021/ic702373b. Epub 2008 Mar 15.

DOI:10.1021/ic702373b
PMID:18345600
Abstract

Water-soluble Co (III) and Co (II) complexes with P- or N-coordinated PTA or PTA oxide ligands, respectively, have been prepared and fully characterized, constituting the first examples of cobalt compounds bearing PTA or any ligand with a cage-like PTA core, the latter complex providing also the first PTA oxide coordination to a metal center.

摘要

分别制备并全面表征了与P配位或N配位的PTA或PTA氧化物配体形成的水溶性Co(III)和Co(II)配合物,它们是带有PTA或任何具有笼状PTA核心配体的钴化合物的首例,后一种配合物也是首例金属中心与PTA氧化物配位的情况。

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Extending the coordination chemistry of 1,3,5-triaza-7-phosphaadamantane (PTA) to cobalt centers: first examples of co-PTA complexes and of a metal complex with the PTA oxide ligand.将1,3,5-三氮杂-7-磷杂金刚烷(PTA)的配位化学扩展至钴中心:共PTA配合物以及含PTA氧化物配体的金属配合物的首例。
Inorg Chem. 2008 Apr 21;47(8):2922-4. doi: 10.1021/ic702373b. Epub 2008 Mar 15.
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Synthesis and coordination chemistry of a novel bidentate phosphine: 6-(diphenylphosphino)-1,3,5-triaza-7-phosphaadamantane (PTA-PPh2).一种新型双齿膦:6-(二苯基膦基)-1,3,5-三氮杂-7-磷杂金刚烷(PTA-PPh2)的合成与配位化学
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Complexes of the [Re(6)(mu(3)-Se)(8)](2+) core-containing clusters with the water-soluble 1,3,5-triaza-7-phosphaadamantane (PTA) ligand: unexpected ligand protonation and related studies.
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Manganese complexes of 1,3,5-triaza-7-phosphaadamantane (PTA): the first nitrogen-bound transition-metal complex of PTA.1,3,5-三氮杂-7-磷杂金刚烷(PTA)的锰配合物:首个氮配位的PTA过渡金属配合物
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Insertion of CO2, ketones, and aldehydes into the C-Li bond of 1,3,5-triaza-7-phosphaadamantan-6-yllithium.将二氧化碳、酮类和醛类插入1,3,5-三氮杂-7-磷杂金刚烷-6-基锂的碳-锂键中。
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Synthesis and structures of nickel and palladium salicylaldiminato 1,3,5-triaza-7-phosphaadamantane (PTA) complexes.镍和钯水杨醛亚胺基-1,3,5-三氮杂-7-磷杂金刚烷(PTA)配合物的合成与结构
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Oxorhenium complexes bearing the water-soluble tris(pyrazol-1-yl)methanesulfonate, 1,3,5-triaza-7-phosphaadamantane, or related ligands, as catalysts for Baeyer-Villiger oxidation of ketones.含水溶性三(吡唑-1-基)甲烷磺酸盐、1,3,5-三氮杂-7-磷金刚烷或相关配体的铱配合物作为酮的 Baeyer-Villiger 氧化反应的催化剂。
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Synthesis of the water soluble ligands dmPTA and dmoPTA and the complex [RuClCp(HdmoPTA)(PPh(3))](OSO(2)CF(3)) (dmPTA = N,N'-Dimethyl-1,3,5-triaza-7-phosphaadamantane, dmoPTA = 3,7-Dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane, HdmoPTA = 3,7-H-3,7-Dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane).水溶性配体dmPTA和dmoPTA以及配合物[RuClCp(HdmoPTA)(PPh(3))](OSO(2)CF(3))的合成(dmPTA = N,N'-二甲基-1,3,5-三氮杂-7-磷杂金刚烷,dmoPTA = 3,7-二甲基-1,3,7-三氮杂-5-磷杂双环[3.3.1]壬烷,HdmoPTA = 3,7-H-3,7-二甲基-1,3,7-三氮杂-5-磷杂双环[3.3.1]壬烷)。
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