将1,3,5-三氮杂-7-磷杂金刚烷（PTA）的配位化学扩展至钴中心：共PTA配合物以及含PTA氧化物配体的金属配合物的首例。
Extending the coordination chemistry of 1,3,5-triaza-7-phosphaadamantane (PTA) to cobalt centers: first examples of co-PTA complexes and of a metal complex with the PTA oxide ligand.
作者信息
Jaremko Lukasz, Kirillov Alexander M, Smoleński Piotr, Lis Tadeusz, Pombeiro Armando J L
机构信息
Centro Química Estrutural, Complexo I, Instituto Superior Técnico, TU Lisbon, Avenida Rovisco Pais, 1049-001 Lisbon, Portugal.
出版信息
Inorg Chem. 2008 Apr 21;47(8):2922-4. doi: 10.1021/ic702373b. Epub 2008 Mar 15.
Water-soluble Co (III) and Co (II) complexes with P- or N-coordinated PTA or PTA oxide ligands, respectively, have been prepared and fully characterized, constituting the first examples of cobalt compounds bearing PTA or any ligand with a cage-like PTA core, the latter complex providing also the first PTA oxide coordination to a metal center.
分别制备并全面表征了与P配位或N配位的PTA或PTA氧化物配体形成的水溶性Co(III)和Co(II)配合物，它们是带有PTA或任何具有笼状PTA核心配体的钴化合物的首例，后一种配合物也是首例金属中心与PTA氧化物配位的情况。
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