Karaca H, Nas S
Department of Food Engineering, Ankara University, Faculty of Engineering, Diskapi, Ankara, Turkey.
Food Addit Contam. 2006 May;23(5):502-8. doi: 10.1080/02652030600550739.
Dried figs of three different categories, palatable, fluorescent, and cull, were investigated for their contents of aflatoxins (B(1), B(2), G(1) and G(2)), patulin, and ergosterol. Samples were obtained from four fig processing plants located in a major fig producing area in the Aegean Region in Turkey. Affinity column clean-up methods were employed for aflatoxins. All aflatoxins, patulin, and ergosterol were determined using high performance liquid chromatography. Palatable figs contaminated with trace amounts of aflatoxins, patulin, and ergosterol, so they posed no risk for the consumer when national and/or international regulatory limits were considered. Fluorescent figs were contaminated with high (117.9-471.9 ppb) aflatoxin levels and cull figs with high patulin (39.3-151.6 ppb) and ergosterol (4.5-18 ppm) levels. The total aflatoxins content was significantly correlated with the patulin content (r(2) = 0.813, p < 0.002) and the ergosterol content (r(2) = 0.920, p < 0.002) only in fluorescent figs. However there was no significant correlation between patulin and ergosterol contents of fluorescent figs. Furthermore, there were no significant correlations between the contents of any two of the three substances in cull figs. This is the first report on the presence of patulin and its co-occurrence with aflatoxin in dried figs.
对三种不同等级的干无花果进行了研究,分别是美味型、荧光型和次果型,检测其黄曲霉毒素(B₁、B₂、G₁和G₂)、展青霉素和麦角固醇的含量。样本取自土耳其爱琴海地区一个主要无花果产区的四家无花果加工厂。采用亲和柱净化法检测黄曲霉毒素。所有黄曲霉毒素、展青霉素和麦角固醇均使用高效液相色谱法测定。美味型无花果被微量的黄曲霉毒素、展青霉素和麦角固醇污染,因此,从国家和/或国际监管限量来看,它们对消费者不构成风险。荧光型无花果被高含量(117.9 - 471.9 ppb)的黄曲霉毒素污染,次果型无花果则被高含量(39.3 - 151.6 ppb)的展青霉素和(4.5 - 18 ppm)的麦角固醇污染。仅在荧光型无花果中,总黄曲霉毒素含量与展青霉素含量(r² = 0.813,p < 0.002)和麦角固醇含量(r² = 0.920,p < 0.002)显著相关。然而,荧光型无花果中展青霉素和麦角固醇含量之间没有显著相关性。此外,次果型无花果中这三种物质中任意两种的含量之间也没有显著相关性。这是关于干无花果中展青霉素及其与黄曲霉毒素共存情况的首次报道。